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2010/1 Module Catalogue
 Module Code: ENG2020 Module Title: CHEMICAL REACTION ENGINEERING 1
Module Provider: Civil, Chemical & Enviromental Eng Short Name: SE2206
Level: HE2 Module Co-ordinator: MILLINGTON CA Dr (C, C & E Eng)
Number of credits: 10 Number of ECTS credits: 5
 
Module Availability
Autumn Semester
Assessment Pattern

Unit(s) of Assessment

 

 

Weighting Towards Module Mark (%)

 

Class Tests (4 x 45 minutes tests)

 

 

20%

 

 

Unseen examination (Open Book) 2 hrs                               

 

 

80%

 

 

Qualifying Condition(s) 

 

 

A weighted aggregate mark of 40% is required to pass the module.

 

 

Module Overview

The heart of a chemical process is often said to be the reactor and a sound understanding the unit’s performance is a pre-requisite for the process design.  This module covers both chemical kinetics of homogeneous systems and the design of reactors processing such systems.  The rate of reaction defined explicitly in terms of system volume combined material and energy balances permit the sizes of reactors processing homogeneous systems but with different idealised flow regimes can be determined.

 

 

 

Prerequisites/Co-requisites

Successful completion of Level HE1of Chemical and Bio-systems Engineering or the Chemical Engineering programmes.

 

 

 

Module Aims

To provide the student with:

 

 

·      a systematic understanding of homogeneous chemical reaction kinetics including both free radical and catalysed reactions.

 

 

·       a comprehensive understanding of the methodology of linking chemical kinetics with material and energy conservation in the design of idealised homogeneous chemical reactors operating both in batch and continuous modes and under both isothermally and non-isothermally conditions.

 

 

·       a superficial understanding of the analysis of non ideal flow and, using the Danckwerts flow model, a knowledge of its effect on an idealised reactor design and sampling   

 

 

 

Learning Outcomes

Upon successful completion of this module you will be able to:

 

·       generate both differential and integrated rate equations for homogeneous chemical reactions

 

·       correctly interpret experimental concentration-time data and from it propose appropriate kinetic equation

 

·       explain the operation of homogeneous Batch, CSTR and Plug Flow reactors and confidently propose the appropriate reactor for a specified duty

 

·       propose a design methodology and then correctly solve the volumetric design of homogeneous Batch, CSRT and plug flow reactors processing simple reversible and irreversible reactions operating under both isothermal and non-isothermal conditions

 

·       understand the complexity of reactor design and to recognise your own limitations.

 

·       explain the need for safe design and the responsibilities of the designer of chemical reactors

 

 

Module Content

Reaction Kinetics

 

            Introduction and nomenclature, reaction rate, order and rate constant

 

            Integrated rate equations

 

            Experimental determination of reaction order

 

            Reversible reactions

 

            Complex reactions - simultaneous (parallel) and consecutive (series)

 

            Effect of temperature on rate constant – Arrhenius' equation

 

            Free radicals and free radical reactions

 

            Branched and non-branching reactions

 

            Bodenstein theory - H2/Br2 reaction

 

            Introduction to catalysis, homogeneous & heterogeneous catalysis

 

 

Reactor Design

 

            Introduction to reactor design

 

            Batch Reactors           types uses and design equations

 

                                                isothermal and non-isothermal design

 

            Continuous Stirred Tank Reactors     uses, perfect mixing, design equations

 

                                                                        single tank design

 

                                                                        multiple tank algebraic and graphical design

 

            Plug Flow Reactors    uses and design equations

 

                                                isothermal design

 

                                                non-isothermal design

 

 

Methods of Teaching/Learning

36 hours of lectures/tutorials, 3 hours of class tests, 2 hour examination and 59 hours of independent learning.

 

Total student learning time 100 hours

 

 

A comprehensive set of tutorial problems will be issued but no pre-printed notes are distributed - students are required to write their own notes during and after lectures

 

 

Selected Texts/Journals

Essential Reading :   None

 

 

Required Reading:   Leverspiel O., Chemical Reaction Engineering, 3nd Edition, John Wiley & Sons Inc., , 1999. (ISBN 0-471-25424-X).

 

Cooper A.R. and Jeffreys G.V., Chemical Kinetics and Reactor Design, Oliver and Boyd, Edinburgh , 1971. (ISBN 0 05 002114 1) – available in the Library

 

 

Recommended Reading :     None

Last Updated

5 October 2010