The following topics will be covered in this course:
1) electronic configuration of atoms and the periodic table (RJ Curry)
- hydrogen atom and origin of 4 quantum numbers n, l, ml, and spin
- aufbau, Pauli, principle and Hund’s rule (electronic configuration) and period table
2) atomic bonding, organic molecules and their properties (RJ Curry)
- Octet ‘rule’ and atomic bonding
- hydrogen molecule bonding and anti-bonding molecular energy levels
- carbon molecules, hybridisation and pi/pi* states
- LCAO and Huckle approximations
3) properties of molecular orbitals (RJ Curry)
- optical properties and relation to LCAO theory
- excited/charged states (excitons, polarons etc)
- experimental measurements of these properties
4) molecular electronics (RJ Curry)
- simple models of molecules and effect of contacts on electronic state
- molecular wires, resistors, diodes, capacitors and transistors
- simple molecular devices and their fabrication and measurement
5) Functional groups and molecules (RJ Curry)
- electron donating and withdrawing groups
- dipoles
6) molecular materials for thin film devices (M Shkunov)
- common electronic molecules and their properties
- thin films deposition techniques and morphology
7) characterisation of organic materials and their electronic properties (M Shkunov)
- surface and bulk characterisation techniques
- chemical composition and structure analysis in relation to electronic properties
8) liquid crystals and self-assembly techniques for organic electronic devices (M Shkunov)
- fundamentals of liquid crystals and their properties
- self-assembly mechanisms
- applications in devices and measurements of characteristics
9) electronic properties of molecular/polymer thin films (M Shkunov)
- effects of morphology and charge transport mechanisms
- experimental methods for measuring charge mobility
- organic field–effect transistors
10) bulk organic and polymer devices (M Shkunov)
- charge injection, Fermi level alignment, and heterojunctions
- Organic Light Emitting Diodes (OLEDs) and lasers
- RFID, FETs, e-paper, OPV devices
- Challenges for molecular electronics